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Published:Journal of Chromatographic Science,
ISSN 0021-9665Volume
44, Number 3, March 2006, pp. 162-166
Applications of Deactivated GC Columns for Analysis of Nitrogen-Containing
Chemicals Related to the Chemical Weapons Convention
Sophie Le Moullec, Yannick Juillet, Arlette Bégos, and
Bruno Bellier
Département Analyse Chimique, Centre d’études du Bouchet,
BP 3 - 5 rue Lavoisier, 91710 Vert-le-Petit, France
Nitrogen-containing chemicals are one of the important families
of compounds relevant to the purposes of the Chemical Weapons Convention (CWC).
Several applications, using various injection modes, of new deactivated columns
specially designed for basic compounds are presented. These columns prove remarkably
well-suited to the gas chromatographic (GC) analysis of the chemicals of interest,
even to underivatized amino-alcohols, whose analysis on conventional GC columns
is often difficult and hindered by poor resolution and high detection limits.
Such a deactivated phase can even replace the typical GC phases used for CWC
verification purposes.
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