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Article Abstracts

Published:Journal of Chromatographic Science, ISSN 0021-9665Volume 44, Number 3, March 2006, pp. 162-166

Applications of Deactivated GC Columns for Analysis of Nitrogen-Containing Chemicals Related to the Chemical Weapons Convention

Sophie Le Moullec, Yannick Juillet, Arlette Bégos, and Bruno Bellier
Département Analyse Chimique, Centre d’études du Bouchet, BP 3 - 5 rue Lavoisier, 91710 Vert-le-Petit, France

Nitrogen-containing chemicals are one of the important families of compounds relevant to the purposes of the Chemical Weapons Convention (CWC). Several applications, using various injection modes, of new deactivated columns specially designed for basic compounds are presented. These columns prove remarkably well-suited to the gas chromatographic (GC) analysis of the chemicals of interest, even to underivatized amino-alcohols, whose analysis on conventional GC columns is often difficult and hindered by poor resolution and high detection limits. Such a deactivated phase can even replace the typical GC phases used for CWC verification purposes.

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