Comprehensive Two-Dimensional Gas Chromatography for Fast Screening of Wash Oils

Published: Journal of Chromatographic Science, ISSN 0021-9665 Volume 41, Number 10, November/December 2003, pp. 506-518

K. Sun[1], W. Winniford[1], J. Griffith[1], K. Colura[1], S. Green[1], M. Pursch[2], and J. Luong[3]
[1]The Dow Chemical Company, Freeport, TX 77531;
[2]Dow Deutschland GmbH & OHG, Analytical Sciences, 77836 Rheinmuenster, Germany; and
[3]Dow Chemical Canada, Fort Saskatchewan, Alberta, Canada

Fast screening of wash oils is demonstrated using comprehensive two-dimensional gas chromatography (GCxGC). Wash oils are used in ethylene production plants to minimize compressor fouling. The composition of a wash oil determines its effectiveness in solubilizing heavy hydrocarbons. In particular, the relative amount of 1- and 2-ring aromatics is important. The presence of oxygenates is undesirable because of adverse effects to the process. It is shown that GCxGC is well suited for this application. Species in wash oils are separated and grouped into three bands: a nonpolar aliphatics band, 1- and 2-ring aromatics band, and polyaromatics band. For a given polar secondary column, the spacing between bands in the second dimension can be adjusted in a broad range by selecting a primary column and an oven-temperature-programming rate. Integration of GCxGC peaks is evaluated using a standard GC integration program and a new GCxGC integration program. Consistent results are obtained using both programs for well-separated GCxGC peaks with relative differences for individual peak ranging from 0.04% to 1.6%. Peak responses are integrated by the GCxGC software, and the relative amounts of aromatics content and aliphatics content are estimated by peak response percent with relative standard deviations ranging from 0.15% to 2.8% (n = 3).

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