Published: Journal of Chromatographic Science, Volume 34, Number 12, December 1996, pp. 547–549.
Forecasting Retention Times in
Temperature-Programmed Gas Chromatography: Experimental
Verification of the Hypothesis on Compound Behavior
E.J. Cavalli and C. Guinchard
The hypothesis of a theoretical “slicing” of the column in temperature-programmed gas chromatography for the accurate forecasting of retention time is tested by actually “slicing” a column. Calculated and observed retention times in relation to the column length are in good agreement.
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