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Published: Journal of Chromatographic Science, Volume 33, Number 6, June 1995, pp. 309-315.

Determination of Alkyllead and Alkyltin Compounds in Solid Samples by Supercritical and Subcritical Fluid Extraction and MEKC
K. Li and S.F.Y. Li

The supercritical and subcritical fluid extraction of alkyllead and alkyltin compounds is investigated using chlorodifluoromethane as the solvent. The separation and determination of extracts from solid samples are performed using micellar electrokinetic capillary chromatography. Optimal extraction conditions are obtained. The subcritical fluid extraction–micellar electrokinetic capillary chromatographic method is applied for the determination of alkyllead and alkyltin compounds in soil and polyvinyl chloride plastic samples.

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